Physics:Quantum Angular momentum operator: Difference between revisions

From ScholarlyWiki
Jump to navigation Jump to search
imported>WikiHarold
Repair Quantum Collection B backlink template
Apply continuous Quantum previous-next navigation
 
(6 intermediate revisions by 2 users not shown)
Line 1: Line 1:
{{Short description|Quantum-mechanical operator associated with rotational symmetry}}
{{Short description|Quantum-mechanical operator associated with rotational symmetry}}


{{Quantum book backlink|Mathematical structure and systems}}
{{Quantum book backlink|Mathematical structure and systems}}
In [[Physics:quantum mechanics|quantum mechanics]], the '''angular momentum operator''' is the operator associated with rotational motion and rotational symmetry, and is the quantum analogue of [[Physics:Angular momentum|angular momentum]] in classical mechanics. Classically, angular momentum is described by a vector <math>\mathbf{L} = (L_x, L_y, L_z)</math>, whose components can all be specified simultaneously. In quantum mechanics, these components become operators <math>\hat{L}_x, \hat{L}_y, \hat{L}_z</math>, representing measurements of angular momentum along each axis. However, unlike in classical physics, these operators do not commute, satisfying relations such as <math>[\hat{L}_x, \hat{L}_y] = i\hbar \hat{L}_z</math> (and cyclic permutations), which implies that the components <math>L_x, L_y, L_z</math> cannot be simultaneously known exactly. Instead, one can simultaneously determine the total angular momentum <math>\hat{L}^2 = \hat{L}_x^2 + \hat{L}_y^2 + \hat{L}_z^2</math> and a single component, usually <math>\hat{L}_z</math>. Quantum states are therefore labeled by the quantum numbers <math>\ell</math> (total angular momentum) and <math>m</math> (its projection along a chosen axis). Geometrically, this corresponds to a situation in which the magnitude of the angular momentum vector is well-defined while only one of its directional components is sharp, so the vector cannot be assigned a definite direction in three-dimensional space. Instead, it is often visualized as lying on a sphere of fixed radius (set by <math>L^2</math>) with uncertainty in its orientation, forming a “cone” of possible directions. As an [[Physics:Observable|observable]], angular momentum is represented by operators whose eigenstates correspond to states with definite angular momentum, and whose eigenvalues give the possible results of measurement; it plays a central role in atomic physics, molecular physics, spectroscopy, and quantum theory more generally.
{{Quantum article nav|previous=Physics:Quantum Noether theorem|previous label=Noether theorem|next=Physics:Quantum Runge–Lenz vector|next label=Runge–Lenz vector}}


Angular momentum is one of the fundamental conserved quantities of motion, together with [[Physics:Angular momentum|linear momentum]] and [[Physics:Energy|energy]].<ref name="Liboff">Introductory Quantum Mechanics, [[Richard L. Liboff]], 2nd Edition, {{ISBN|0-201-54715-5}}</ref> In quantum mechanics, several related angular momentum operators appear:
<div style="display:flex; gap:24px; align-items:flex-start; max-width:1200px;">


* the '''orbital angular momentum''' operator, usually denoted <math>\mathbf{L}</math>,
<div style="width:280px;">
* the '''spin angular momentum''' operator, usually denoted <math>\mathbf{S}</math>,
__TOC__
* the '''total angular momentum''' operator, usually denoted <math>\mathbf{J}</math>.
</div>


These are related by
<div style="flex:1; line-height:1.45; color:#006b45; column-count:2; column-gap:32px; column-rule:1px solid #b8d8c8;">
<math display="block">\mathbf{J}=\mathbf{L}+\mathbf{S}.</math>
'''Angular momentum operator''' in quantum mechanics, the angular momentum operator is the operator associated with rotational motion and rotational symmetry, and is the quantum analogue of angular momentum in classical mechanics. Geometrically, this corresponds to a situation in which the magnitude of the angular momentum vector is well-defined while only one of its directional components is sharp, so the vector cannot be assigned a definite direction in three-dimensional space. Instead, it is often visualized as lying on a sphere of fixed radius (set by L^2) with uncertainty in its orientation, forming a “cone” of possible directions. As an observable, angular momentum is represented by operators whose eigenstates correspond to states with definite angular momentum, and whose eigenvalues give the possible results of measurement; it plays a central role in atomic physics, molecular physics, spectroscopy, and quantum theory more generally. Angular momentum is one of the fundamental conserved quantities of motion, together with linear momentum and energy. Depending on context, the expression angular momentum operator may refer either to orbital angular momentum or to total angular momentum. For a closed system, the total angular momentum is conserved, in accordance with rotational symmetry and Noether's theorem. In quantum mechanics, angular momentum appears in three closely related forms: orbital angular momentum, spin angular momentum, and total angular momentum.
</div>
 
<div style="width:300px;">
[[File:Quantum angular momentum operator in physics.jpg|thumb|280px|Quantum Angular momentum operator.]]
</div>
 
</div>


Depending on context, the expression ''angular momentum operator'' may refer either to orbital angular momentum or to total angular momentum. For a closed system, the total angular momentum is conserved, in accordance with rotational symmetry and [[Physics:Noether's theorem|Noether's theorem]].
[[File:Quantum angular momentum operator in physics.jpg|thumb|450px]]
{{quantum mechanics}}
==Overview==
==Overview==
[[File:LS coupling (corrected).png|thumb|250x250px|''Vector cones'' of total angular momentum <math>\mathbf{J}</math> (green), orbital angular momentum <math>\mathbf{L}</math> (blue), and spin angular momentum <math>\mathbf{S}</math> (red). The cone structure reflects the fact that not all components can be known simultaneously; see [[#Visual interpretation|Visual interpretation]].]]
[[File:LS coupling (corrected).png|thumb|250x250px|''Vector cones'' of total angular momentum <math>\mathbf{J}</math> (green), orbital angular momentum <math>\mathbf{L}</math> (blue), and spin angular momentum <math>\mathbf{S}</math> (red). The cone structure reflects the fact that not all components can be known simultaneously; see [[#Visual interpretation|Visual interpretation]].]]
Line 24: Line 28:
The classical angular momentum of a particle is
The classical angular momentum of a particle is
<math display="block">\mathbf{L}=\mathbf{r}\times\mathbf{p}.</math>
<math display="block">\mathbf{L}=\mathbf{r}\times\mathbf{p}.</math>
The same formal expression holds in quantum mechanics, except that <math>\mathbf{r}</math> and <math>\mathbf{p}</math> are now the [[Physics:Position operator|position operator]] and [[Physics:Momentum operator|momentum operator]]:
The same formal expression holds in quantum mechanics, except that <math>\mathbf{r}</math> and <math>\mathbf{p}</math> are now the position operator and momentum operator:
<math display="block">\mathbf{L}=\mathbf{r}\times\mathbf{p}.</math>
<math display="block">\mathbf{L}=\mathbf{r}\times\mathbf{p}.</math>


Thus <math>\mathbf{L}</math> is a [[vector operator]], with components
Thus <math>\mathbf{L}</math> is a vector operator, with components
<math display="block">\mathbf{L}=(L_x,L_y,L_z).</math>
<math display="block">\mathbf{L}=(L_x,L_y,L_z).</math>


Line 35: Line 39:


===Spin angular momentum===
===Spin angular momentum===
{{main|Physics:Spin}}
''Related topic:'' Spin


In addition to orbital angular momentum, quantum systems may possess an intrinsic form of angular momentum called '''spin''', represented by
In addition to orbital angular momentum, quantum systems may possess an intrinsic form of angular momentum called '''spin''', represented by
Line 46: Line 50:
<math display="block">\mathbf{J}=\mathbf{L}+\mathbf{S}.</math>
<math display="block">\mathbf{J}=\mathbf{L}+\mathbf{S}.</math>


For a closed system, the total angular momentum is conserved. By contrast, <math>\mathbf{L}</math> and <math>\mathbf{S}</math> need not be conserved separately. For example, in [[Physics:Spin–orbit interaction|spin–orbit interaction]], angular momentum may be exchanged between orbital and spin parts while the total <math>\mathbf{J}</math> remains constant.
For a closed system, the total angular momentum is conserved. By contrast, <math>\mathbf{L}</math> and <math>\mathbf{S}</math> need not be conserved separately. For example, in spin–orbit interaction, angular momentum may be exchanged between orbital and spin parts while the total <math>\mathbf{J}</math> remains constant.


==Commutation relations==
==Commutation relations==
Line 53: Line 57:
The components of the orbital angular momentum operator satisfy the commutation relations<ref>{{cite book|chapter-url=https://books.google.com/books?id=dRsvmTFpB3wC&pg=PA171|title=Quantum Mechanics|first=G.|last=Aruldhas|page=171|chapter=formula (8.8)|isbn=978-81-203-1962-2|date=2004-02-01|publisher=Prentice Hall India}}</ref>
The components of the orbital angular momentum operator satisfy the commutation relations<ref>{{cite book|chapter-url=https://books.google.com/books?id=dRsvmTFpB3wC&pg=PA171|title=Quantum Mechanics|first=G.|last=Aruldhas|page=171|chapter=formula (8.8)|isbn=978-81-203-1962-2|date=2004-02-01|publisher=Prentice Hall India}}</ref>
<math display="block">[L_x,L_y]=i\hbar L_z,\qquad [L_y,L_z]=i\hbar L_x,\qquad [L_z,L_x]=i\hbar L_y,</math>
<math display="block">[L_x,L_y]=i\hbar L_z,\qquad [L_y,L_z]=i\hbar L_x,\qquad [L_z,L_x]=i\hbar L_y,</math>
where the [[commutator]] is defined by
where the commutator is defined by
<math display="block">[X,Y]\equiv XY-YX.</math>
<math display="block">[X,Y]\equiv XY-YX.</math>


Line 71: Line 75:
[J_l,J_m]=i\hbar\sum_{n=1}^{3}\varepsilon_{lmn}J_n.</math>
[J_l,J_m]=i\hbar\sum_{n=1}^{3}\varepsilon_{lmn}J_n.</math>


These commutation relations show that angular momentum operators generate the Lie algebra associated with three-dimensional rotations, usually written in physics as the algebra of [[Physics:SU(2) color superconductivity|SU(2)]] or [[SO(3)]].
These commutation relations show that angular momentum operators generate the Lie algebra associated with three-dimensional rotations, usually written in physics as the algebra of SU(2) or SO(3).


===Commutation relations involving the magnitude===
===Commutation relations involving the magnitude===
Line 83: Line 87:
<math display="block">[S^2,S_i]=0,\qquad [J^2,J_i]=0.</math>
<math display="block">[S^2,S_i]=0,\qquad [J^2,J_i]=0.</math>


Mathematically, <math>L^2</math> is a [[Casimir element|Casimir invariant]] of the rotation algebra.
Mathematically, <math>L^2</math> is a Casimir invariant of the rotation algebra.


===Uncertainty principle===
===Uncertainty principle===
{{main|Uncertainty principle}}
''Related topic:'' Uncertainty principle


Because different components of angular momentum do not commute, they cannot in general be measured simultaneously with arbitrary precision. For example, the Robertson–Schrödinger relation gives
Because different components of angular momentum do not commute, they cannot in general be measured simultaneously with arbitrary precision. For example, the Robertson–Schrödinger relation gives
Line 95: Line 99:


==Quantization==
==Quantization==
{{see also|Physics:Azimuthal quantum number|Physics:Magnetic quantum number}}
''Related topic:'' Azimuthal quantum number, Magnetic quantum number


In quantum mechanics, angular momentum is quantized: only certain discrete measurement results are allowed. For orbital angular momentum,
In quantum mechanics, angular momentum is quantized: only certain discrete measurement results are allowed. For orbital angular momentum,
Line 132: Line 136:


===Derivation using ladder operators===
===Derivation using ladder operators===
{{main|Physics:Ladder_operator#Angular_momentum}}
''Related topic:'' Angular_momentum


A standard derivation of the allowed values uses the ladder operators
A standard derivation of the allowed values uses the ladder operators
Line 155: Line 159:


==Angular momentum as the generator of rotations==
==Angular momentum as the generator of rotations==
{{see also|Physics:Total angular momentum quantum number}}
''Related topic:'' Total angular momentum quantum number


The most fundamental characterization of angular momentum is that it generates rotations.<ref name=littlejohn>{{cite web|url=http://bohr.physics.berkeley.edu/classes/221/1011/notes/spinrot.pdf|title=Lecture notes on rotations in quantum mechanics|first=Robert|last=Littlejohn|access-date=13 Jan 2012|work=Physics 221B Spring 2011|year=2011|archive-date=26 August 2014|archive-url=https://web.archive.org/web/20140826003155/http://bohr.physics.berkeley.edu/classes/221/1011/notes/spinrot.pdf|url-status=dead}}</ref> If <math>R(\hat{n},\phi)</math> denotes the operator that rotates a system by an angle <math>\phi</math> about the axis <math>\hat{n}</math>, then the angular momentum component along that axis is defined by
The most fundamental characterization of angular momentum is that it generates rotations.<ref name=littlejohn>{{cite web|url=http://bohr.physics.berkeley.edu/classes/221/1011/notes/spinrot.pdf|title=Lecture notes on rotations in quantum mechanics|first=Robert|last=Littlejohn|access-date=13 Jan 2012|work=Physics 221B Spring 2011|year=2011|archive-date=26 August 2014|archive-url=https://web.archive.org/web/20140826003155/http://bohr.physics.berkeley.edu/classes/221/1011/notes/spinrot.pdf|url-status=dead}}</ref> If <math>R(\hat{n},\phi)</math> denotes the operator that rotates a system by an angle <math>\phi</math> about the axis <math>\hat{n}</math>, then the angular momentum component along that axis is defined by
Line 166: Line 170:
Thus angular momentum governs how quantum states transform under rotations.
Thus angular momentum governs how quantum states transform under rotations.


[[File:RotationOperators.svg|thumb|300px|Different kinds of [[Physics:Rotation operator (quantum mechanics)|rotation operators]]]].
[[File:RotationOperators.svg|thumb|300px|Different kinds of rotation operators]].
{{ordered list
{{ordered list
  | list-style-type = upper-alpha
  | list-style-type = upper-alpha
Line 183: Line 187:


===SU(2), SO(3), and 360° rotations===
===SU(2), SO(3), and 360° rotations===
{{main|Physics:Spin}}
''Related topic:'' Spin


In classical mechanics, a rotation by <math>360^\circ</math> is identical to doing nothing. In quantum mechanics, however, a state with half-integer total angular momentum may change sign under a full <math>360^\circ</math> rotation:
In classical mechanics, a rotation by <math>360^\circ</math> is identical to doing nothing. In quantum mechanics, however, a state with half-integer total angular momentum may change sign under a full <math>360^\circ</math> rotation:
Line 191: Line 195:
for integer <math>j</math>.<ref name=littlejohn/>
for integer <math>j</math>.<ref name=littlejohn/>


This reflects the fact that quantum rotations are described by [[SU(2)]], which is the double cover of [[SO(3)]]. Orbital angular momentum, by contrast, corresponds to ordinary spatial rotations and therefore only allows integer quantum numbers.
This reflects the fact that quantum rotations are described by SU(2), which is the double cover of SO(3). Orbital angular momentum, by contrast, corresponds to ordinary spatial rotations and therefore only allows integer quantum numbers.


===Connection to representation theory===
===Connection to representation theory===
{{main|Physics:Particle physics and representation theory|Representation theory of SU(2)|Rotation group SO(3)#A note on Lie algebras}}
''Related topic:'' Particle physics and representation theory, Representation theory of SU(2), A note on Lie algebras


When rotation operators act on quantum states, they define a representation of the rotation group. Correspondingly, angular momentum operators define a representation of the associated Lie algebra. The classification of possible angular momentum quantum numbers is therefore a representation-theoretic problem for [[Physics:SU(2) color superconductivity|SU(2)]] and [[SO(3)]].
When rotation operators act on quantum states, they define a representation of the rotation group. Correspondingly, angular momentum operators define a representation of the associated Lie algebra. The classification of possible angular momentum quantum numbers is therefore a representation-theoretic problem for SU(2) and SO(3).


===Connection to commutation relations===
===Connection to commutation relations===
Line 202: Line 206:


==Conservation of angular momentum==
==Conservation of angular momentum==
If the [[Hamiltonian (quantum mechanics)|Hamiltonian]] <math>H</math> is rotationally invariant, then angular momentum is conserved. Rotational invariance means
If the Hamiltonian <math>H</math> is rotationally invariant, then angular momentum is conserved. Rotational invariance means
<math display="block">RHR^{-1}=H,</math>
<math display="block">RHR^{-1}=H,</math>
where <math>R</math> is a rotation operator. This implies
where <math>R</math> is a rotation operator. This implies
Line 209: Line 213:
<math display="block">[H,\mathbf{J}]=\mathbf{0}.</math>
<math display="block">[H,\mathbf{J}]=\mathbf{0}.</math>


By the [[Ehrenfest theorem]], the total angular momentum is then conserved. For a spinless particle in a [[central potential]], this reduces to conservation of orbital angular momentum. When spin is present, spin–orbit coupling may transfer angular momentum between <math>\mathbf{L}</math> and <math>\mathbf{S}</math>, while the total <math>\mathbf{J}</math> remains conserved.
By the Ehrenfest theorem, the total angular momentum is then conserved. For a spinless particle in a central potential, this reduces to conservation of orbital angular momentum. When spin is present, spin–orbit coupling may transfer angular momentum between <math>\mathbf{L}</math> and <math>\mathbf{S}</math>, while the total <math>\mathbf{J}</math> remains conserved.


==Angular momentum coupling==
==Angular momentum coupling==
{{main|Physics:Angular momentum coupling|Physics:Clebsch–Gordan coefficients}}
''Related topic:'' Angular momentum coupling, Clebsch–Gordan coefficients


When a system contains multiple sources of angular momentum, the individual contributions may combine to form a conserved total angular momentum. For example, for two angular momenta <math>\mathbf{J}_1</math> and <math>\mathbf{J}_2</math>,
When a system contains multiple sources of angular momentum, the individual contributions may combine to form a conserved total angular momentum. For example, for two angular momenta <math>\mathbf{J}_1</math> and <math>\mathbf{J}_2</math>,
Line 220: Line 224:
<math display="block">j\in\{|j_1-j_2|,\ |j_1-j_2|+1,\ldots,j_1+j_2\}.</math>
<math display="block">j\in\{|j_1-j_2|,\ |j_1-j_2|+1,\ldots,j_1+j_2\}.</math>


Transformations between uncoupled and coupled angular momentum bases are described by [[Physics:Clebsch–Gordan coefficients|Clebsch–Gordan coefficients]]. In atomic and molecular physics, this structure underlies term symbols and the classification of energy levels.
Transformations between uncoupled and coupled angular momentum bases are described by Clebsch–Gordan coefficients. In atomic and molecular physics, this structure underlies term symbols and the classification of energy levels.


==Orbital angular momentum in spherical coordinates==
==Orbital angular momentum in spherical coordinates==
Angular momentum operators naturally arise in problems with spherical symmetry. In the position representation and [[spherical coordinates]], the orbital angular momentum operator is<ref>{{Cite book
Angular momentum operators naturally arise in problems with spherical symmetry. In the position representation and spherical coordinates, the orbital angular momentum operator is<ref>{{Cite book
  | publisher = Springer Berlin Heidelberg
  | publisher = Springer Berlin Heidelberg
  | last = Bes
  | last = Bes
Line 249: Line 253:
\end{align}</math>
\end{align}</math>


The angular part of the [[Laplace operator]] can be written in terms of <math>L^2</math>:
The angular part of the Laplace operator can be written in terms of <math>L^2</math>:
<math display="block">\Delta=\frac{1}{r^2}\frac{\partial}{\partial r}\left(r^2\frac{\partial}{\partial r}\right)-\frac{L^2}{\hbar^2 r^2}.</math>
<math display="block">\Delta=\frac{1}{r^2}\frac{\partial}{\partial r}\left(r^2\frac{\partial}{\partial r}\right)-\frac{L^2}{\hbar^2 r^2}.</math>


Line 259: Line 263:
with wavefunctions
with wavefunctions
<math display="block">\langle \theta,\phi|\ell,m\rangle=Y_{\ell,m}(\theta,\phi),</math>
<math display="block">\langle \theta,\phi|\ell,m\rangle=Y_{\ell,m}(\theta,\phi),</math>
where <math>Y_{\ell,m}</math> are the [[spherical harmonics]].<ref>Sakurai, JJ & Napolitano, J (2010), ''[[Modern Quantum Mechanics]]'' (2nd edition), Pearson, {{ISBN|978-0805382914}}</ref>
where <math>Y_{\ell,m}</math> are the spherical harmonics.<ref>Sakurai, JJ & Napolitano, J (2010), ''Modern Quantum Mechanics'' (2nd edition), Pearson, {{ISBN|978-0805382914}}</ref>


==See also==
==See also==
{{#invoke:PhysicsQC|tocHeadingAndList|Physics:Quantum basics/See also}}
{{#invoke:PhysicsQC|tocHeadingAndList|Physics:Quantum basics/See also}}
{{colbegin}}
{{colbegin}}
* [[Physics:Runge–Lenz vector|Runge–Lenz vector]]
* Runge–Lenz vector
* [[Holstein–Primakoff transformation]]
* Holstein–Primakoff transformation
* [[Jordan map]]
* Jordan map
* [[Pauli–Lubanski pseudovector]]
* Pauli–Lubanski pseudovector
* [[Angular momentum diagrams (quantum mechanics)]]
* Angular momentum diagrams (quantum mechanics)
* [[Spherical basis]]
* Spherical basis
* [[Tensor operator]]
* Tensor operator
* [[Orbital magnetization]]
* Orbital magnetization
* [[Orbital angular momentum of free electrons]]
* Orbital angular momentum of free electrons
* [[Orbital angular momentum of light]]
* Orbital angular momentum of light
{{colend}}
{{colend}}


Line 296: Line 300:
[[Category:Rotational symmetry]]
[[Category:Rotational symmetry]]


{{Sourceattribution|Quantum Angular momentum operator|1}}
{{Sourceattribution|Physics:Quantum Angular momentum operator|1}}

Latest revision as of 21:58, 20 May 2026



← Previous : Noether theorem
Next : Runge–Lenz vector →

Angular momentum operator in quantum mechanics, the angular momentum operator is the operator associated with rotational motion and rotational symmetry, and is the quantum analogue of angular momentum in classical mechanics. Geometrically, this corresponds to a situation in which the magnitude of the angular momentum vector is well-defined while only one of its directional components is sharp, so the vector cannot be assigned a definite direction in three-dimensional space. Instead, it is often visualized as lying on a sphere of fixed radius (set by L^2) with uncertainty in its orientation, forming a “cone” of possible directions. As an observable, angular momentum is represented by operators whose eigenstates correspond to states with definite angular momentum, and whose eigenvalues give the possible results of measurement; it plays a central role in atomic physics, molecular physics, spectroscopy, and quantum theory more generally. Angular momentum is one of the fundamental conserved quantities of motion, together with linear momentum and energy. Depending on context, the expression angular momentum operator may refer either to orbital angular momentum or to total angular momentum. For a closed system, the total angular momentum is conserved, in accordance with rotational symmetry and Noether's theorem. In quantum mechanics, angular momentum appears in three closely related forms: orbital angular momentum, spin angular momentum, and total angular momentum.

Quantum Angular momentum operator.

Overview

Vector cones of total angular momentum 𝐉 (green), orbital angular momentum 𝐋 (blue), and spin angular momentum 𝐒 (red). The cone structure reflects the fact that not all components can be known simultaneously; see Visual interpretation.

In quantum mechanics, angular momentum appears in three closely related forms: orbital angular momentum, spin angular momentum, and total angular momentum.

Orbital angular momentum

The classical angular momentum of a particle is 𝐋=𝐫×𝐩. The same formal expression holds in quantum mechanics, except that 𝐫 and 𝐩 are now the position operator and momentum operator: 𝐋=𝐫×𝐩.

Thus 𝐋 is a vector operator, with components 𝐋=(Lx,Ly,Lz).

For a single spinless, uncharged particle in the position representation, 𝐋=i(𝐫×), where is the gradient operator.

Spin angular momentum

Related topic: Spin

In addition to orbital angular momentum, quantum systems may possess an intrinsic form of angular momentum called spin, represented by 𝐒=(Sx,Sy,Sz).

Spin has no exact classical counterpart. It is often illustrated as if a particle were spinning about an axis, but this picture is only heuristic; spin is an intrinsic quantum property.[1] Elementary particles have fixed intrinsic spin: for example, electrons have spin 12, while photons have spin 1.

Total angular momentum

The total angular momentum operator combines orbital and spin contributions: 𝐉=𝐋+𝐒.

For a closed system, the total angular momentum is conserved. By contrast, 𝐋 and 𝐒 need not be conserved separately. For example, in spin–orbit interaction, angular momentum may be exchanged between orbital and spin parts while the total 𝐉 remains constant.

Commutation relations

Commutation relations between components

The components of the orbital angular momentum operator satisfy the commutation relations[2] [Lx,Ly]=iLz,[Ly,Lz]=iLx,[Lz,Lx]=iLy, where the commutator is defined by [X,Y]XYYX.

In index notation, [Ll,Lm]=in=13εlmnLn, or, using Einstein summation convention, [Ll,Lm]=iεlmnLn.

These relations can also be written compactly as[3] 𝐋×𝐋=i𝐋.

They follow from the canonical commutation relations [xl,pm]=iδlm.

The same algebra holds for spin and total angular momentum: [Sl,Sm]=in=13εlmnSn,[Jl,Jm]=in=13εlmnJn.

These commutation relations show that angular momentum operators generate the Lie algebra associated with three-dimensional rotations, usually written in physics as the algebra of SU(2) or SO(3).

Commutation relations involving the magnitude

The square of the orbital angular momentum operator is defined by L2Lx2+Ly2+Lz2.

This operator commutes with each component of 𝐋: [L2,Lx]=[L2,Ly]=[L2,Lz]=0.

Thus one may simultaneously specify the values of L2 and one chosen component, usually Lz. The same property holds for spin and total angular momentum: [S2,Si]=0,[J2,Ji]=0.

Mathematically, L2 is a Casimir invariant of the rotation algebra.

Uncertainty principle

Related topic: Uncertainty principle

Because different components of angular momentum do not commute, they cannot in general be measured simultaneously with arbitrary precision. For example, the Robertson–Schrödinger relation gives σLxσLy2|Lz|, where σX is the standard deviation of measurements of X, and X is the expectation value.

Thus two orthogonal components, such as Lx and Ly, are complementary observables. By contrast, L2 and one component such as Lz can be measured simultaneously.

Quantization

Related topic: Azimuthal quantum number, Magnetic quantum number

In quantum mechanics, angular momentum is quantized: only certain discrete measurement results are allowed. For orbital angular momentum,

Quantity Allowed values Notes
L2 2(+1), where =0,1,2, is the orbital or azimuthal quantum number.
Lz m, where m=,+1,, m is the magnetic quantum number.
S2 2s(s+1), where s=0,12,1,32, s is the spin quantum number.
Sz ms, where ms=s,s+1,,s ms is the spin projection quantum number.
J2 2j(j+1), where j=0,12,1,32, j is the total angular momentum quantum number.
Jz mj, where mj=j,j+1,,j mj is the total angular momentum projection quantum number.

For orbital angular momentum, both and m are always integers. For spin and total angular momentum, half-integer values are also possible.

Derivation using ladder operators

Related topic: Angular_momentum

A standard derivation of the allowed values uses the ladder operators J+Jx+iJy,JJxiJy.

If |ψ is a simultaneous eigenstate of J2 and Jz, then J+|ψ and J|ψ are either zero or new simultaneous eigenstates with the same value of J2 but with the Jz eigenvalue shifted by ±. Repeated application of these operators leads to the quantization rules above.

Since 𝐋 obeys the same algebra as 𝐉, the same ladder-operator argument applies to orbital angular momentum. In the case of 𝐋, single-valuedness of the wavefunction in the azimuthal angle ϕ imposes the further restriction that and m must be integers.

Visual interpretation

Heuristic vector model of orbital angular momentum.

Although angular momentum in quantum mechanics is represented by operators rather than classical vectors, it is often illustrated heuristically by vectors of fixed length whose tip can lie only on a cone. For a state with given and m, the magnitude is |L|=L2=(+1), while the component Lz has the definite value Lz=m.

The uncertainty in the transverse components Lx and Ly is represented by the circular spread around the cone.

Quantization in macroscopic systems

The same quantum rules apply in principle to macroscopic bodies. In practice, however, the allowed steps in angular momentum are so small compared with the total angular momentum of ordinary objects that the spectrum appears continuous for all observable purposes.

Angular momentum as the generator of rotations

Related topic: Total angular momentum quantum number

The most fundamental characterization of angular momentum is that it generates rotations.[4] If R(n^,ϕ) denotes the operator that rotates a system by an angle ϕ about the axis n^, then the angular momentum component along that axis is defined by Jn^ilimϕ0R(n^,ϕ)1ϕ=iR(n^,ϕ)ϕ|ϕ=0.

Equivalently, R(n^,ϕ)=exp(iϕJn^).

Thus angular momentum governs how quantum states transform under rotations.

Different kinds of rotation operators

.

]]

The orbital and spin operators similarly generate spatial and internal rotations: Rspatial(n^,ϕ)=exp(iϕLn^), Rinternal(n^,ϕ)=exp(iϕSn^).

The relation 𝐉=𝐋+𝐒 reflects the corresponding decomposition of a full rotation into spatial and internal parts.

SU(2), SO(3), and 360° rotations

Related topic: Spin

In classical mechanics, a rotation by 360 is identical to doing nothing. In quantum mechanics, however, a state with half-integer total angular momentum may change sign under a full 360 rotation: R(n^,360)=1 for half-integer j, whereas R(n^,360)=+1 for integer j.[4]

This reflects the fact that quantum rotations are described by SU(2), which is the double cover of SO(3). Orbital angular momentum, by contrast, corresponds to ordinary spatial rotations and therefore only allows integer quantum numbers.

Connection to representation theory

Related topic: Particle physics and representation theory, Representation theory of SU(2), A note on Lie algebras

When rotation operators act on quantum states, they define a representation of the rotation group. Correspondingly, angular momentum operators define a representation of the associated Lie algebra. The classification of possible angular momentum quantum numbers is therefore a representation-theoretic problem for SU(2) and SO(3).

Connection to commutation relations

Rotations about different axes do not commute. This noncommutativity is reflected at the operator level in the angular momentum commutation relations. Thus the algebra of angular momentum is a direct expression of the geometry of rotations in three-dimensional space.

Conservation of angular momentum

If the Hamiltonian H is rotationally invariant, then angular momentum is conserved. Rotational invariance means RHR1=H, where R is a rotation operator. This implies [H,R]=0, and therefore [H,𝐉]=𝟎.

By the Ehrenfest theorem, the total angular momentum is then conserved. For a spinless particle in a central potential, this reduces to conservation of orbital angular momentum. When spin is present, spin–orbit coupling may transfer angular momentum between 𝐋 and 𝐒, while the total 𝐉 remains conserved.

Angular momentum coupling

Related topic: Angular momentum coupling, Clebsch–Gordan coefficients

When a system contains multiple sources of angular momentum, the individual contributions may combine to form a conserved total angular momentum. For example, for two angular momenta 𝐉1 and 𝐉2, 𝐉=𝐉1+𝐉2.

The corresponding total quantum number satisfies j{|j1j2|, |j1j2|+1,,j1+j2}.

Transformations between uncoupled and coupled angular momentum bases are described by Clebsch–Gordan coefficients. In atomic and molecular physics, this structure underlies term symbols and the classification of energy levels.

Orbital angular momentum in spherical coordinates

Angular momentum operators naturally arise in problems with spherical symmetry. In the position representation and spherical coordinates, the orbital angular momentum operator is[5] 𝐋=i(θ^sin(θ)ϕϕ^θ)=i(𝐱^(sin(ϕ)θ+cot(θ)cos(ϕ)ϕ)+𝐲^(cos(ϕ)θ+cot(θ)sin(ϕ)ϕ)𝐳^ϕ),L+=eiϕ(θ+icot(θ)ϕ),L=eiϕ(θ+icot(θ)ϕ),L2=2(1sin(θ)θ(sin(θ)θ)+1sin2(θ)2ϕ2),Lz=iϕ.

The angular part of the Laplace operator can be written in terms of L2: Δ=1r2r(r2r)L22r2.

The simultaneous eigenstates of L2 and Lz satisfy L2|,m=2(+1)|,m,Lz|,m=m|,m, with wavefunctions θ,ϕ|,m=Y,m(θ,ϕ), where Y,m are the spherical harmonics.[6]

See also

Table of contents (198 articles)

Index

Full contents

9. Quantum optics and experiments (5) Back to index
Experimental quantum physics: qubits, dilution refrigerators, quantum communication, and laboratory systems.
Experimental quantum physics: qubits, dilution refrigerators, quantum communication, and laboratory systems.
14. Plasma and fusion physics (8) Back to index
Conceptual illustration of plasma physics in a fusion context, showing magnetically confined ionized gas in a tokamak and the collective behavior governed by electromagnetic fields and transport processes.
Conceptual illustration of plasma physics in a fusion context, showing magnetically confined ionized gas in a tokamak and the collective behavior governed by electromagnetic fields and transport processes.
  • Runge–Lenz vector
  • Holstein–Primakoff transformation
  • Jordan map
  • Pauli–Lubanski pseudovector
  • Angular momentum diagrams (quantum mechanics)
  • Spherical basis
  • Tensor operator
  • Orbital magnetization
  • Orbital angular momentum of free electrons
  • Orbital angular momentum of light


Notes

References

  1. Ohanian, Hans C. (1986-06-01). "What is spin?". American Journal of Physics 54 (6): 500–505. doi:10.1119/1.14580. ISSN 0002-9505. Bibcode1986AmJPh..54..500O. https://physics.mcmaster.ca/phys3mm3/notes/whatisspin.pdf. 
  2. Aruldhas, G. (2004-02-01). "formula (8.8)". Quantum Mechanics. Prentice Hall India. p. 171. ISBN 978-81-203-1962-2. https://books.google.com/books?id=dRsvmTFpB3wC&pg=PA171. 
  3. Shankar, R. (1994). Principles of Quantum Mechanics (2nd ed.). New York: Kluwer Academic / Plenum. p. 319. ISBN 9780306447907. https://archive.org/details/principlesquantu00shan_139. 
  4. 4.0 4.1 Littlejohn, Robert (2011). "Lecture notes on rotations in quantum mechanics". Physics 221B Spring 2011. http://bohr.physics.berkeley.edu/classes/221/1011/notes/spinrot.pdf. 
  5. Bes, Daniel R. (2007). Quantum Mechanics. Advanced Texts in Physics. Berlin, Heidelberg: Springer Berlin Heidelberg. p. 70. doi:10.1007/978-3-540-46216-3. ISBN 978-3-540-46215-6. Bibcode2007qume.book.....B. 
  6. Sakurai, JJ & Napolitano, J (2010), Modern Quantum Mechanics (2nd edition), Pearson, ISBN 978-0805382914

Further reading

Author: Harold Foppele