Biography:Robert S. Mulliken: Difference between revisions

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{{Short description|American physical chemist and founder of molecular orbital theory}}
{{Short description|American physical chemist and founder of molecular orbital theory}}
{{Biography page}}
{{Infobox scientist
{{Infobox scientist
| name = Robert S. Mulliken
| name = Robert S. Mulliken

Revision as of 17:34, 24 May 2026


Robert S. Mulliken
Mulliken in 1929
Mulliken in 1929
Born 7 June 1896
Newburyport, Massachusetts, United States
Died 31 October 1986
Arlington, Virginia, United States


Known for Molecular orbital theory; Mulliken population analysis; electronegativity scale
Awards Nobel Prize in Chemistry (1966); Priestley Medal (1983)

Robert Sanderson Mulliken (7 June 1896 - 31 October 1986) was an American physical chemist who played a central role in the development of molecular orbital theory. His work made molecular spectra and chemical bonding part of a unified quantum-mechanical picture.

Mulliken received the 1966 Nobel Prize in Chemistry for fundamental work concerning chemical bonds and the electronic structure of molecules by the molecular orbital method.[1]

Molecular orbital theory

Mulliken treated electrons in molecules as occupying orbitals spread over the whole molecule rather than only localized between pairs of atoms. This approach became essential for explaining spectroscopy, delocalized bonding, antibonding orbitals, and computational chemistry.

In the Quantum Collection, Mulliken is linked with:

Influence

Mulliken's work helped bridge experimental spectroscopy and theoretical quantum chemistry. Concepts such as molecular orbitals, population analysis, and orbital symmetry remain central in modern chemical physics.

See also

References


Author: Harold Foppele